Vanadium(II) (V<sup>2+</sup>) has an electron configuration that is derived from its neutral atom vanadium (V).
Neutral Vanadium (V): The electron configuration of neutral vanadium (atomic number 23) is [Ar] 3d<sup>3</sup>4s<sup>2</sup>.
Vanadium(II) (V<sup>2+</sup>): When vanadium forms a 2+ ion, it loses two electrons. These electrons are removed from the outermost shell first, which are the 4s electrons. Therefore, the electron configuration of V<sup>2+</sup> becomes [Ar] 3d<sup>3</sup>.
Important Aspects:
[Argon Core]: The "[Ar]" represents the filled electron configuration of argon, which is 1s<sup>2</sup>2s<sup>2</sup>2p<sup>6</sup>3s<sup>2</sup>3p<sup>6</sup>.
d-Orbital Configuration: The 3d<sup>3</sup> configuration indicates that there are three electrons in the 3d orbitals. These electrons will typically occupy the d-orbitals individually according to Hund's%20Rule to minimize electron-electron repulsion.
Paramagnetism: Because V<sup>2+</sup> has unpaired electrons (three of them), it is paramagnetic. This means it is attracted to magnetic fields.
Color: Aqueous solutions of V<sup>2+</sup> are typically violet in color due to d-d transitions.
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